2-Bromo-2-methyl-N-p-tolyl­propanamide

نویسندگان

  • Rodolfo Moreno-Fuquen
  • David E. Quintero
  • Fabio Zuluaga
  • Alan R. Kennedy
  • Regina H. De Almeida Santos
چکیده

In the title mol-ecule, C(11)H(14)BrNO, there is twist between the mean plane of the amide group and the benzene ring [C(=O)-N-C C torsion angle = -31.2 (5)°]. In the crystal, inter-molecular N-H⋯O and weak C-H⋯O hydrogen bonds link mol-ecules into chains along [100]. The methyl group H atoms are disordered over two sets of sites with equal occupancy.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and Antimicrobial Profile of Newer Schiff Bases and Thiazolidinone Derivatives

Esterification of p-bromo-m-cresol led to formation of 2-(4-bromo-3-methylphenoxy)acetate (1). 2-(4-Bromo-3-methyl phenoxy)acetohydrazide (2) is derived from Compound (1) by hydrazination. Compound (2) was reacted with different aromatic aldehydes to yield N-(substituted benzylidiene)-2-(4-bromo-3-methyl phenoxy)acetamide(3a-c). Cyclization of compound (3a-c) with thioglycolic acid yielded 2-(4...

متن کامل

A Sandmeyer type reaction for bromination of 2-mercapto-1-methyl-imidazoline (N2C4H6S) into 2-bromo-1-methyl-imidazole (N2C4H5Br) in presence of copper(I) bromide.

2-Mercapto-1-methyl-imidazoline (N(2)C(4)H(6)S) is converted at room temperature into 2-bromo-1-methyl-imidazole (N(2)C(4)H(5)Br) in presence of copper(I) bromide in acetonitrile-chloroform mixture via extrusion of sulfur as sulfate and oxidation of Cu(I) into Cu(II). 2-Bromo-1-methyl-imidazole was isolated as its self assembled tetranuclear Cu(II) cluster, [Cu(4)(η(1)-N-(N(2)C(4)H(5)Br)(4)(μ(4...

متن کامل

Synthesis and spectral characterisation of Mn(II) complexes with amide group containing 1,8-Naphthyridines

Complexes of Mn(II) with 1,8-naphthyride containing amide group ligands 2-amino1-8,naphthyride-3-carboxamide (ANC), 2-amino-N-phenyl-1,8-naphthyride-3-carboxamide (APNC), 2-amino-N-(p-methyl phenyl)-1,8-naphthyridine-3-carboxamide(AMPNC), 2-amino-N-)p-bromo phenyl)1,8-naphthyridine-3-carboxamide(ABPNC), 2-amino-N-(p-chloro phenyl)-1,8-naphthyridine3-carboxamide (ACPNC), 2-amino-N-(p-methoxy phe...

متن کامل

A Novel Initiator of [5-(benzyloxy)-4-oxo-4H-pyran-2-yl]methyl-2-bromo-2-methylpropanoateas in Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate

A novel nano-initiator containing kojic acid moiety, [5-(benzyloxy)-4-oxo-4H-pyran-2-yl)methyl-2-bromo-2-methylpropanoate was synthesized by the reaction of 5-(benzyloxy)-2-(hydroxymethyl)-4H-pyran-4-one with 2-bromoisobutyryl bromide in triethylamine and used as initiator in the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate in the presence of Cu(0)/CuCl2and N,N...

متن کامل

Preparation of Shortened Norbelladine Analogs

The preparation of N-[(2-bromo-5-hydroxy-4-methoxyphenyl)methyl]-N-[(4hydroxyphenyl)methyl]formamide (5) and 2-bromo-5-hydroxy-α-[(4-hydroxyphenyl)methyl]-4-methoxypropaneamide (10) is reported.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011